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Inherent chirality : ウィキペディア英語版
Inherent chirality
In chemistry, inherent chirality is a property of molecules and complexes whose lack of symmetry does not originate from a classic stereogenic element, but is rather the consequence of the presence of a curvature in a structure that would be devoid of symmetry axes in any bidimensional representation.〔''Inherently chiral concave molecules—from synthesis'' to applications Agnieszka Szumna Chem. Soc. Rev., 2010, 39, 4274-4285 〕
The expression "inherently chiral" was first used by Boehmer to describe calixarenes with XXYZ or WXYZ substitution patterns at the upper rim, and has been later extended to fullerenes with a chiral molecular framework, like C76, C78, and C84, non symmetric uranyl-salophen complexes and the protonated Schiff base of 11-cis-retinal, the chromophore of rhodopsin.
== See also ==

*Chirality (chemistry)

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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